Studies on C-Nor-D-homosteroids. X. Conversion of Normal Steroids to C-Nor-D-homosteroids
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چکیده
منابع مشابه
D-nor steroids: anomalous conformation and reactivity of C-D-cis D-norandrostanes.
The C/D-cisD-norandrostanes 1a, 1b, 1c, 2a, 2b, and 2c were prepared and their reactivity studied. Whereas carbonium ion reactions of 1b and 1c are readily interpreted on the basis of their assigned stereochemistry, reactions of 2b and 2c suggest that these compounds react via conformations in which the 16beta-substituents are pseudoequatorial, requiring a ring C boat conformation as shown in f...
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ژورنال
عنوان ژورنال: Chemical and Pharmaceutical Bulletin
سال: 1974
ISSN: 0009-2363,1347-5223
DOI: 10.1248/cpb.22.1046